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Spec mapping: OCR H556 Module 4.1 — Charge and current (electric current as the rate of flow of charge, I=ΔQ/Δt; the coulomb as the SI unit of charge; the elementary charge e=1.60×10−19 C; charge quantisation Q=ne; conventional current vs electron flow; the ampere as an SI base unit). Refer to the official OCR H556 specification document for exact wording.
Electric charge and electric current sit at the foundation of the entire Module 4 syllabus. Every later topic — drift velocity (lesson 2), Kirchhoff's laws (lessons 3 and 11), Ohm's law (lesson 5), I-V characteristics (lesson 6), resistivity (lesson 7), internal resistance (lesson 9), potential dividers (lesson 12), capacitor charging (Module 6.1) and even the photoelectric effect (Module 4.5) — rests on the two definitions in this single lesson.
This lesson tightens those definitions to A* depth. We treat charge as a quantised property of matter rather than a fluid; we treat current as the time-derivative of charge transported across a surface, not "the amount of electricity"; we untangle the confusing-but-conventional sign convention that Franklin saddled us with in 1747; and we end with worked OCR-style problems and a specimen 6-mark question.
Electric charge (symbol Q) is one of the small handful of fundamental properties of matter — alongside mass, spin, and lepton number — that is conserved in every known interaction. It is measured in coulombs (C) in SI. Charge comes in two varieties, positive and negative: like charges repel via the Coulomb interaction, unlike charges attract, and the magnitude of the force is governed by Coulomb's law (Module 6.2).
The charge carriers you will encounter at A-Level are summarised below.
| Particle | Sign | Magnitude of charge |
|---|---|---|
| Electron | Negative | e=1.60×10−19 C |
| Proton | Positive | +e=+1.60×10−19 C |
| Singly-charged ion (e.g. Na+, Cl−) | Either | e |
| Doubly-charged ion (e.g. Cu2+) | Either | 2e |
| Up quark | +2e/3 (never observed in isolation) | — |
| Down quark | −e/3 (never observed in isolation) | — |
The magnitude e=1.60×10−19 C is called the elementary charge. Since 2019 the SI base units have been redefined so that the numerical value of e is fixed exactly at 1.602176634×10−19 C, and the coulomb is then derived from it. You don't need to memorise the extra digits, but you should know that e is a defining constant rather than something you measure.
Quark charges are fractions of e, but quarks are permanently confined inside hadrons by the strong force — they have never been observed in isolation in any experiment. The smallest free charge anywhere in the universe (as far as we know) is therefore e itself.
One of the deepest empirical facts of physics is that electric charge is quantised. Every observed isolated charge is an integer multiple of e:
Q=±nen=0,1,2,3,…
You cannot have half an electron's charge on a normal object. Even though quarks carry ±e/3 and ±2e/3, they never appear in isolation, so the smallest free charge we ever measure is e.
This was established experimentally by Millikan's oil drop experiment (1909). Millikan balanced tiny charged oil droplets in an electric field between two horizontal plates, varied the field until the droplet hung motionless (so that the upward electrical force balanced gravity), and measured the charge from the equilibrium condition. Repeating with hundreds of droplets, every measured charge came out as an integer multiple of 1.6×10−19 C.
Modern precision experiments confirm Millikan's result to about one part in 1020: charge is genuinely quantised, not "nearly quantised". This is in contrast to mass, which (so far as we know) takes a continuous range of values.
A small isolated metal sphere carries a net charge of −4.8×10−18 C. How many excess electrons does it have?
n=e∣Q∣=1.60×10−194.8×10−18=30 electrons.
Always check: the answer must be a whole number. If you get 30.04, you have a rounding error or a wrong exponent — go back to your working.
A copper ion Cu2+ in an electrolyte cell loses two outer electrons. What is its charge in coulombs?
Q=+2e=+2×1.60×10−19=+3.20×10−19 C.
Doubly-ionised metals are common in electrolysis (Module 4 extends into electrochemistry implicitly through the Faraday constant F=NAe≈9.65×104 C mol−1).
Electric current (symbol I) is the rate of flow of electric charge across a chosen surface. Its SI unit is the ampere (A), one of the seven SI base units.
The precise definition is a time derivative:
I=dtdQor, for steady current,I=ΔtΔQ
For a steady current I flowing for time t, the total charge that has crossed the surface is:
Q=It.
One coulomb is the charge transported by a steady current of one ampere in one second:
1 C=1 A s.
The ampere itself is a base unit (one of seven), and the coulomb is a derived unit built from it.
Conceptual point: Current is a flow rate, not "an amount of electricity". A river analogy is helpful: charge is the volume of water that has passed a bridge; current is the litres-per-second rate. You cannot store current — you store charge. You drive current by maintaining a potential difference.
A current of 0.25 A flows through a resistor for 2.0 minutes. Calculate the total charge transferred and the corresponding number of electrons.
About 2×1020 electrons cross every cross-section of the wire in just two minutes — twenty thousand billion billion charge carriers. Electrical circuits handle staggering numbers of carriers per second.
A capacitor is charging through a resistor. The current is I(t)=0.10e−t/2.0 A, with t in seconds. How much charge has flowed in the first 4.0 s?
Q=∫04.0I(t)dt=∫04.00.10e−t/2.0dt=0.10×[−2.0e−t/2.0]04.0
=0.10×2.0×(1−e−2.0)=0.20×(1−0.135)=0.173 C.
You won't be asked to evaluate exponential integrals at AS — but the graphical interpretation matters: the area under an I-t graph equals the charge transferred. This idea generalises Q = It to currents that vary with time, and it returns in lesson 6 (Module 6.1, capacitor discharge).
When Benjamin Franklin defined the direction of current flow in the 1740s, the electron had not yet been discovered (J. J. Thomson identified it in 1897). Franklin made an arbitrary choice — that current flows from positive to negative — and it stuck. It turned out to be the opposite of the direction in which the negatively-charged electron carriers actually drift in a metal.
We have two compatible-but-inverted ways to describe the same physical reality:
The amount of charge transferred per second is identical in both descriptions; only the labelling differs. Since 1900 the convention has been to always draw arrows in the conventional-current direction in circuit diagrams. This is the convention OCR mark schemes enforce.
flowchart LR
BP["Battery (+)"] --> W1[Wire] --> R[Resistor] --> W2[Wire] --> BN["Battery (-)"]
BN -.->|"actual electron drift"| BP
The dashed line above shows the physical electron drift direction; the solid arrows show the conventional current direction. Both are correct descriptions of the same circuit.
You might ask: now that we know electrons move the "wrong way", why don't we just redefine the convention? Several reasons:
Since the 2019 SI redefinition, the ampere is defined by fixing the numerical value of the elementary charge:
e=1.602176634×10−19 C exactly.
The ampere is then "the current corresponding to a flow of 1/e≈6.241×1018 elementary charges per second". The coulomb is derived: 1 C=1 A s.
Before 2019 the ampere was defined by the magnetic force between two parallel current-carrying wires, but that definition has now been retired. You are not expected to recite the new SI definition at A-Level, but you should know:
To measure current you use an ammeter, connected in series with the component whose current you want to measure. An ideal ammeter has zero resistance, so that inserting it does not disturb the circuit.
Real ammeters have a small but non-zero resistance: a cheap multimeter on the 10 A range may have ∼0.01 Ω, while a laboratory digital meter may be effectively zero at the precision needed for A-Level work.
flowchart LR
B[Battery] --> A((Ammeter)) --> R[Resistor] --> B
Never connect an ammeter in parallel across a cell or a resistor. Because the ammeter has very low resistance, doing so creates a near short-circuit, drawing a huge current that can destroy the meter, burn its fuse, melt insulation, or damage the cell.
The contrast with voltmeter use is sharp: ammeters go in series, voltmeters go in parallel (lesson 4). Mixing them up is one of the classic OCR experimental-design errors.
For Module 4 we deal almost entirely with direct current (DC): the current flows in one direction with a constant (or slowly varying) magnitude. Batteries, dry cells, solar cells and lab DC power supplies all provide DC.
Alternating current (AC) changes direction periodically — in the UK mains supply at 50 Hz, so 100 reversals every second. The current is sinusoidal: I(t)=I0sin(2πft) with f=50 Hz. AC is studied in detail in Module 6.3 (alternating currents). For Module 4 all our calculations are DC unless stated otherwise.
A useful unifying point: at any instant, the AC current I(t) has a well-defined value, and Kirchhoff's first law (lesson 3) and the definition I=dQ/dt both still apply. AC is just DC with I varying sinusoidally with time.
A capacitor is charged by a steady current of 15 mA for 4.0 s. Calculate:
(a) The charge delivered.
(b) The number of electrons that passed through the wire.
(c) If the capacitor has capacitance C=100 μF, what is the final pd across its plates?
(a) Q=It=15×10−3×4.0=0.060 C =60 mC.
(b) n=Q/e=0.060/(1.60×10−19)=3.75×1017 electrons.
(c) From Q=CV (Module 6.1): V=Q/C=0.060/(100×10−6)=600 V.
Notice the consistent use of base units throughout: mA was converted to A before substitution; μF was converted to F before division. OCR mark schemes are strict about base-unit working; forgetting to convert remains one of the single most common errors in calculations at this level.
To build intuition, here is a rough ladder of electrical currents you might encounter.
| Scale | Typical current |
|---|---|
| Quantum-coherence experiment (single-electron transistor) | ∼10 fA (10−14 A) |
| Nerve impulse | ∼10 pA (10−11 A) |
| Wristwatch | ∼1 μA (10−6 A) |
| LED indicator | ∼20 mA (0.02 A) |
| Torch bulb | ∼0.2 A |
| Domestic kettle (UK mains, 3 kW at 230 V) | ∼13 A |
| Domestic ring main rating | 30 A |
| Car starter motor | ∼200 A |
| Arc-welding electrode | ∼500 A |
| Lightning strike (peak) | ∼30 kA (3×104 A) |
| Particle accelerator beam current | ∼1 mA but at 109 V |
The relation Q=It means that even tiny currents over long times can transfer enormous charge (a nanoamp over a year transfers ∼0.03 C), and very large currents over short times can do huge amounts of damage — hence the importance of fuses and circuit breakers in real installations. A 30 A fuse will blow within milliseconds if a short pulls a current beyond its rating, isolating the fault before the wiring overheats.
A 2.0 kW electric kettle is plugged into the UK 230 V mains supply and boils a litre of water in 3.0 minutes. Calculate the total charge that flows through the heating element.
Nearly 1022 electrons cross the heating element to boil one kettle. This is roughly the number of stars in the observable universe — to boil tea.
Question (6 marks): A car battery is rated as "60 A h" (60 ampere-hours), meaning it can deliver 60 A for 1 h before its terminal voltage drops below a usable level.
(a) Explain what is meant by "current is the rate of flow of charge". [1]
(b) Calculate the total charge stored in a fully-charged 60 A h battery. [2]
(c) Estimate the total number of electrons that pass through the battery during a complete discharge. The elementary charge is e=1.60×10−19 C. [3]
| Mark | AO | Awarded for |
|---|---|---|
| 1 | AO1 | Definition: current I equals charge ΔQ transferred per unit time Δt (I=ΔQ/Δt). |
| 2 | AO2 | Conversion: 1 h =3600 s, so Q=It=60×3600. |
| 3 | AO2 | Q=2.16×105 C. |
| 4 | AO2 | n=Q/e identified as the equation needed. |
| 5 | AO2 | n=2.16×105/1.60×10−19. |
| 6 | AO3 | n≈1.35×1024 electrons, with appropriate sig figs and units. |
AO split: AO1 = 1, AO2 = 4, AO3 = 1.
(a) Current is how much charge flows.
(b) Q=It=60×1=60 C.
(c) Number of electrons =60/1.6×10−19=3.75×1020.
Examiner commentary: The next-band move is unit consistency — treating "1 hour" as "1" rather than converting to seconds. The candidate's Q=60 C is exactly the charge in one second of 60 A current, not in one hour. Mark 1 partial (definition gets the qualitative idea but misses "per unit time" / time-rate), Mark 2 lost (no second-conversion), Mark 3 lost (numerical value wrong by factor of 3600), Mark 4 awarded (correct equation n=Q/e), Mark 5 lost (uses the wrong Q), Mark 6 partial (arithmetic is internally consistent but the wrong starting value). A reliable mid-band trap: failing to convert hours to seconds is the single most common SI-units error in OCR electricity papers.
(a) Current is the rate of flow of electric charge, I=ΔQ/Δt.
(b) Convert: 1 h =3600 s. Q=It=60×3600=216000 C.
(c) Number of electrons: n=Q/e=216000/1.60×10−19=1.35×1024 electrons.
Examiner commentary: The next-band move is more precise unit and significant-figure handling — writing Q=2.16×105 C in standard form, and explicitly stating "approximately" in (c) given the rating is itself an approximation. The candidate has all the physics right and would gain Marks 1, 2, 3, 4, 5 and most of 6 — losing the sig-fig presentation mark only. This is a solid response that with a touch more polish would hit full marks.
(a) Electric current is defined as the rate of flow of electric charge: I=ΔQ/Δt, with I in amperes when ΔQ is in coulombs and Δt in seconds.
(b) Converting time to SI base units: t=1 h =3600 s. Total charge delivered:
Q=It=60×3600=2.16×105 C.
(c) The total charge corresponds to n=Q/e elementary charges, each carried by one electron:
n=eQ=1.60×10−192.16×105≈1.35×1024 electrons.
This is roughly Avogadro's number times 2 — an entire two moles of electrons cycling through the battery in a single full discharge, which is consistent with the lead-acid battery storing energy electrochemically by displacing two moles of charge per mole of PbO2 reduced.
Examiner commentary: Full marks. The candidate has converted units carefully, used scientific notation consistently, and made the synoptic connection to electrochemistry (mole-counts of electrons) without being asked. The depth shown in the final remark goes beyond what is needed for marks but indicates secure command of the topic.